Polyolefin Reaction Engineering

ISBN: 9783527317103 出版年：2013 页码：355 Joao B P Soares Timothy F L McKenna Wiley

PREFACE INTRODUCTION TO POLYOLEFINS Introduction Polyethylene Resins Polypropylene Resins POLYOLEFIN MICROSTRUCTURAL CHARACTERIZATION Introduction Molecular Weight Distribution Chemical Composition Distribution Cross-Fractionation Techniques Long-Chain Branching POLYMERIZATION CATALYSIS AND MECHANISM Introduction Catalyst Types Supporting Single-Site Catalysts Polymerization Mechanism with Coordination Catalysts POLYOLEFIN REACTORS AND PROCESSES Introduction Reactor Configurations and Design Olefin Polymerization Processes Conclusion POLYMERIZATION KINETICS Introduction Fundamental Model for Polymerization Kinetics Nonstandard Polymerization Kinetics Models Vapor-Liquid-Solid Equilibrium Considerations POLYOLEFIN MICROSTRUCTURAL MODELING Introduction Instantaneous Distributions Monte Carlo Simulation PARTICLE GROWTH AND SINGLE PARTICLE MODELING Introduction Particle Fragmentation and Growth Single Particle Models Limitations of the PFM/MGM Approach: Particle Morphology DEVELOPING MODELS FOR INDUSTRIAL REACTORS Introduction