Activation of Small Molecules —— Organometallic and Bioinorganic Perspectives

----- 小分子活化

ISBN: 9783527313129 出版年：2006 页码：383 William B Tolman Wiley

Preface. List of Contributors. 1 Carbon Dioxide Reduction and Uses as a Chemical Feedstock (Michele Aresta). 1.1 Introduction. 1.2 Properties of the CO2 Molecule. 1.3 CO2 Coordination to Metal Centers and Reactivity of Coordinated CO2. 1.4 CO2 Conversion. 1.5 Conclusions. References. 2 Nitrogen Monoxide and Nitrous Oxide Binding and Reduction (Dong-Heon Lee, Biplab Mondal, and Kenneth D. Karlin). 2.1 Introduction. 2.2 NO. 2.3 N2O. 2.4 Summary and Conclusions. References. 3 Bio-organometallic Approaches to Nitrogen Fixation Chemistry (Jonas C. Peters and Mark P. Mehn). 3.1 Introduction - The N2 Fixation Challenge. 3.2 Biological N2 Reduction. 3.3 Biomimetic Systems that Model Structure and Function. 3.4 Concluding Remarks. References. 4 The Activation of Dihydrogen (Jesse W. Tye and Michael B. Hall). 4.1 Introduction. 4.2 Structure and Bonding of Metal-bound H-Atoms. 4.3 Intramolecular H-Atom Exchange. 4.4 Nonclassical H-Bonds. 4.5 Reactivity of Metal-bound H-Atoms. 4.6 Recent Advances in the Activation of Dihydrogen by Synthetic Complexes. 4.7 Enzymatically Catalyzed Dihydrogen Oxidation and Proton Reduction. 4.8 Conclusions. Acknowledgments. Abbreviations. References. 5 Molecular Oxygen Binding and Activation: Oxidation Catalysis (Candace N. Cornell and Matthew S. Sigman). 5.1 Introduction. 5.2 Additive Coreductants. 5.3 Ligand-modified Catalysis. 5.4 Conclusions and Outlook. References. 6 Dioxygen Binding and Activation: Reactive Intermediates (Andrew S. Borovik, Paul J. Zinn and Matthew K. Zart). 6.1 Introduction. 6.2 Dioxygen Binders. 6.3 Reactive Intermediates: Iron and Copper Species. 6.4 Cobalt-Dioxygen Complexes. 6.5 Manganese-Dioxygen Complexes. 6.6 Nickel-Dioxygen Complexes and Their Reactive Intermediates. 6.7 Summary. Acknowledgments. References. 7 Methane Functionalization (Brian Conley, William J. Tenn, III, Kenneth J.H. Young, Somesh Ganesh, Steve Meier, Jonas Oxgaard, Jason Gonzales, William A. Goddard, III, and Roy A. Periana). 7.1 Methane as a Replacement for Petroleum. 7.2 Low Temperature is Key to Economical Methane Functionalization. 7.3 CH Activation as a Pathway to Economical Methane Functionalization via CH Hydroxylation. 7.4 Conclusions and Perspective for Methane Functionalization. References. 8 Water Activation: Catalytic Hydrolysis (Lisa M. Berreau). 8.1 Introduction. 8.2 Water Activation: Coordination Sphere Effects on M-OH2 Acidity and Structure. 8.3 Secondary H-Bonding Effects on Substrate Coordination, Activation and Catalytic Hydrolysis Involving Phosphate Esters. 8.4 Summary and Future Directions. References. 9 Carbon Monoxide as a Chemical Feedstock: Carbonylation Catalysis (Piet W.N.M. van Leeuwen and Zoraida Freixa). 9.1 Introduction. 9.2 Rhodium-catalyzed Hydroformylation. 9.3 Methanol Carbonylation. 9.4 Concluding Remarks. References. Subject Index.