Crystal-Liquid-Gas Phase Transitions and Thermodynamic Similarity

ISBN: 9783527405763 出版年：2006 页码：186 Vladimir P Skripov Mars Z Faizullin Wiley

Foreword. 1 Introduction. 1.1 Basic Aims and Methods. 1.2 States of Aggregation. Phase Diagrams and the Clausius-Clapeyron Equation. 1.3 Metastable States. Relaxation via Nucleation. 1.4 Phase Transformations in a Metastable Phase. Homogeneous Nucleation. 2 Liquid-Gas Phase Transitions. 2.1 BasicFact: ExistenceofaCriticalPoint. 2.2 Method of Thermodynamic Similarity. 2.3 Similarity Near the Critical Point: The Change of Critical Indices. 2.4 New Universal Relationships for Liquid-Vapor Phase Coexistence in One-Component Systems. 2.4.1 Correlation Between Pressure and Densities of Liquid and Vapor Along the Saturation Curve. 2.4.2 Correlation Between Caloric Properties and Densities of Liquid and VaporAlongtheSaturationCurve. 2.4.3 Correlation Between Surface Tension and Heat of Evaporation of Nonassociated Liquids. 2.4.4 One-Parameter Correlation for the Heat of Evaporation of NonassociatedLiquids. 3 Crystal-Liquid Phase Transitions. 3.1 The Behavior of the Crystal-Liquid Equilibrium Curve at High Pressures. 3.2 Experimental Methods of Investigation of Melting of Substances at High Pressure. 3.3 Application of Similarity Methods for a Description of Melting. 3.4 The Extension of the Melting Curve into the Range of Negative Pressures and the Scaling of Thermodynamic Parameters. 3.5 Internal Pressure in a Liquid Along the Equilibrium Curves with Crystal and Vapor. 3.6 Stability of Thermodynamic States and the Metastable Continuation of the Melting Curves. 3.7 The Behavior of the Viscosity of a Liquid Along the Coexistence Curve with the Crystalline Phase. 3.8 The Behavior of Volume and Entropy Jumps Along the Melting Curve. 3.9 The Surface Tension of Simple Liquids Along the Melting Curve. 3.10 Correlations Between Thermodynamic Properties Characterizing Melting. 3.11 Melting and Crystallization of Small Particles. 3.11.1 Thermodynamic Aspects. 3.11.2 KineticAspects. 4 Phase Transitions in Solutions. 4.1 Generalized Clausius-Clapeyron Equation for Solutions. 4.2 Application of the Generalized Clausius-Clapeyron Equation for the Plot of thePhaseDiagrams. 4.3 Thermodynamic Correlations for Phase-Separating Solutions. 4.4 Experimental Studies of Phase-Separating Solutions. 4.5 Thermodynamic Similarity of Phase-Separating Binary Solutions with Upper Critical Dissolution Temperature. 4.6 Thermodynamic Similarity of Phase-Separating Binary Solutions with Lower Critical Dissolution Temperature. 4.7 Concluding Remarks. A Appendices. A.1 List of Symbols. A.2 SuperscriptsandSubscripts. References. Index.