Functional Synthetic Receptors

ISBN: 9783527306558 出版年：2006 页码：442 Thomas Schrader Andrew D Hamilton Wiley

Preface. List of Contributors. 1 Artif icial (Pseudo)peptides for Molecular Recognition and Catalysis (L. J. Prins, P. Scrimin). 1.1 Introduction. 1.2 Recognition of Biological Targets by Pseudo-peptides. 1.3 Synthetic (Pseudo)peptide-based Supermolecules: From Structure to Function. 1.4 Combinatorial Selection of Functional (Pseudo)peptides. 1.5 Conclusions. References. 2 Carbohydrate Receptors (A. P. Davis, T. D. James). 2.1 Introduction. 2.2 Carbohydrate Receptors Employing Noncovalent Interactions. 2.3 Receptors Employing B-O Bond Formation. References. 3 Ammonium, Amidinium, Guanidinium, and Pyridinium Cations (T. Schrader, M. Maue). 3.1 Introduction. 3.2 Ammonium Cations. 3.3 Amidinium Cations. 3.4 Guanidinium Cations. 3.5 Pyridinium Cations. 3.6 Conclusions and Outlook. References. 4 Artif icial Pyrrole-based Anion Receptors (W.-S. Cho, J. L. Sessler). 4.1 Introduction. 4.2 Anions in Biological Systems. 4.3 Cationic Pyrrole-based Receptors. 4.4 Neutral Pyrrole-based Anion Receptors. 4.5 Anion Carriers in Transport Applications. 4.6 Anion Sensing. 4.7 Guanidinium-based Anion Receptors. 4.8 Amide-based Anion Receptors. 4.9 Urea-based Anion Receptors. 4.10 Conclusions. Acknowledgment. References. 5 Molecular Containers in Action (D. M. Rudkevich). 5.1 Introduction. 5.2 Variety of Molecular Containers. 5.3 Chemistry Inside Capsules. 5.4 Storage of Information Inside Capsules. 5.5 Materials and Sensors by Encapsulation. 5.6 Biologically Relevant Encapsulation. 5.7 Concluding Remarks. Acknowledgment. References. 6 Formation and Recognition Properties of Dynamic Combinatorial Libraries (A. D. Hamilton, D. M. Tagore, K. I. Sprinz). 6.1 Introduction. 6.2 Covalent Interactions Used in DCC Design. 6.3 Noncovalent Interactions Used in DCC Design. 6.4 Conformational/Configurational Isomerization. 6.5 Receptor-based Screening, Selection, and Amplification. 6.6 Conclusions. Acknowledgment. References. 7 Synthetic Molecular Machines (E. R. Kay, D. A. Leigh). 7.1 Introduction. 7.2 Controlling Conformational Changes. 7.3 Controlling Configurational Changes. 7.4 Controlling Motion in Supramolecular Systems. 7.5 Controlling Motion in Interlocked Systems. 7.6 From Laboratory to Technology: Toward Useful Molecular Machines. 7.7 Summary and Outlook. References. 8 Replicable Nanoscaffolded Multifunctionality - A Chemical Perspective (W.-M. Pankau, S. Antsypovich, L. Eckardt, J. Stankiewicz, S. Monninghoff, J. Zimmermann, M. Radeva, G. von Kiedrowski). Abstract. 8.1 Introduction. 8.2 A Manifesto for Nanorobot Implementation. 8.3 Conclusion. Acknowledgment. References. Index.