Platinum and Uranium Hexafluorides: Structural Chemistry, NMR, Thermodynamic and Magnetic Properties, Effects of Spin-Orbit Interactions

ISBN: 9781616688387 出版年：2010 页码：91 Svetlana G Kozlova Svyatoslav P Gabuda Nova Science

This new book reviews research on the thermodynamic, magnetic susceptibility, solid-state 19F NMR and structural data for molecular hexafluorides and hexafluoro complexes related to interpretation of intermolecular interactions and structural properties. Along with conceptual problems associated with the application of methods theoretical and quantum chemistry, this work addresses the relationships between some fundamental properties of coordinate bonding and correlation effects, the electron-density transfer, and corrections for relativistic s-orbital contraction, d- and f-orbital expansion and destabilization and spin-orbit coupling.