Electrolytes

ISBN: 9781482249385 出版年：2014 页码：362 Aseyev, Georgii Georgievich CRC Press

SUPRAMOLECULAR INTERACTIONS Historic Introduction Early Views on the Process of Ion Solvation in Electrolyte Solutions Evolution of Solvation Concepts and Structural State of Electrolyte Solutions References Supramolecular Designing of a Host Stages of Formation of Approaches to the Concept of Long-Range Supermolecular Forces The Principles of Supramolecular-Thermodynamic Approach Quantum Statistics of Supermolecular Interactions Supramolecular Host-Guest Structure Distribution Function Rate of Distribution Function Change in Time Supramolecular Interactions Potential Solving the Equation for Potential in the Absence of External Fields References Thermodynamics of Supermolecular and Supramolecular Interactions Supermolecular-Thermodynamic Interactions of Activity Coefficients Guest Activity Function Minimum Interaction Distance of Electrostatic Forces among Ions in the Host Solution Distance between Ions in the Host Solution Dielectric Permittivity of Host-Guest Solution References Supermolecular Interactions Van der Waals Components of Attraction Potential Perturbation Method Interaction Energy in the First Approximation of the Perturbation Method Evaluation of the Energy of Van der Waals Interactions in Structure Formation of the Guest-Host Solution Ion-Dipole Interactions in the First Approximation of the Perturbation Theory Weak Chemical Interactions in the Host Solution Short-Range Repulsion in the Host Solution Adjustment of Potential of Supramolecular Interactions Thermodynamics of Water Activity Interaction References NON-EQUILIBRIUM PHENOMENA Electrical Conductivity Historic Preamble Theories of Electrical Conductivity General Continuity Equation for Electrolyte Solutions in Perturbed State Electrical Conductivity: General Theory of Supermolecular Forces Relaxation Force Electrophoretic Retardation Electrical Conductivity of Electrolytes at Weak Electric Fields and Low Frequencies Results and Their Discussion References Viscosity Semiempirical Approaches to Viscosity Determination Viscosity Theory General Theory of Viscosity Solution Viscosity Coefficient (General Solving) Solution Viscosity Coefficient (Final Solving) References Diffusion Coefficient About Diffusion Theories Diffusion Flows General Theory of Supermolecular Forces in Diffusion Flows Diffusion Coefficient (Final Solution) References Conclusion