Precision Crystallization —— Theory and Practice of Controlling Crystal Size

----- 精密结晶：控制晶粒大小的理论和实践

ISBN: 9781439806746 出版年：2009 页码：226 Leubner, Ingo CRC Press

Prior Models for Nucleation and Growth The Primitive Model The Total Crystal Number The Classical Nucleation Model (Becker-Doering) Derivation of the Classical Nucleation Model The Klein-Moisar Model Kharitanova Derivation Growth Rate and Maximum Growth Rate The Balanced Nucleation and Growth Model The BNG Model and the Nucleation Phase Assumptions for Modeling Assumptions for Calculations Preliminary Considerations: Nucleation Rate The Balanced Nucleation and Growth Model BNG Modeling of the Nucleation Phase and Size Distribution Reaction Parameters for the Calculations Results and Discussion The Analytical BNG Model Crystal Formation (Nucleation) under Kinetically and Diffusion-Controlled Growth Conditions Kinetically Controlled Nucleation Experiment: Kinetically Controlled Crystal Nucleation Theory Diffusion-Controlled Nucleation Reaction Variables, Constants, Predictions Modeling: Separation of Variables R, Cs, and T Addition Rate Solubility Temperature, T Supersizing with Ripeners Crystal Formation (Nucleation) in the Presence of Ostwald Ripening Agents: Theory Crystal Formation (Nucleation) of Silver Bromide in the Presence of a Di-Thia Crown Ether as an Ostwald Ripening Agent Crystal Formation (Nucleation) of AgClBr (15:85) in the Presence of Ammonia as an Ostwald Ripening Agent Crystal Formation (Nucleation) of AgBrI (97.4:2.6) in the Presence of 1,8-dihydroxy-3,6-dithiaoctane as an Ostwald Ripening Agent Nanosizing with Restrainers Crystal Formation (Nucleation) in the Presence of Growth Restrainers Crystal Growth and Renucleation Crystal Growth, Renucleation, and Maximum Growth Rate: Theory and Experiments Continuous Crystallization Continuous Crystallization in the Mixed-Suspension, Mixed-Product-Removal (MSMPR), or Continuous Stirred Tank Reactor (CSTR) Crystallizer Transient Behavior of Silver Bromide Precipitation in a Continuous Suspension Crystallizer A New Crystal Nucleation Theory for Size Control in Continuous Precipitations Crystal Growth in the Continuous Crystallizer Seeded Precipitations in the Continuous Stirred Tank Reactor Crystallizer Epilogue Glossary of Terms Bibliography Index