Vanadium —— Chemistry, Biochemistry, Pharmacology and Practical Applications

----- 钒：化学、生物化学、药理学与实际应用

ISBN: 9781420046137 出版年：2007 页码：266 Tracey, Alan S Willsky, Gail R Takeuchi, Esther S CRC Press

s INTRODUCTION Background VANADATE SPECIATION Techniques Vanadate Self-Condensation Reactions Vanadium Atom Stoichiometry of Complexes MONODENTATE LIGANDS OF VANADATE Alcohols and Phenols Amines and Acids AQUEOUS REACTIONS OF VANADATE WITH MULTIDENTATE LIGANDS Glycols, a-Hydroxycarboxylic Acids, and Dicarboxylic Acids Hydroxamic Acids Thiolate-Containing Ligands Amino Alcohols and Related Ligands Amino Acids and Derivatives a-Amino Acids and Peptides Other Multidentate Ligands COORDINATION OF VANADATE BY HYDROGEN PEROXIDE AND HYDROXYLAMINES Hydrogen Peroxide Hydroxylamines Coordination Geometry of Peroxo and Hydroxamido Vanadates REACTIONS OF PEROXOVANADATES Heteroligand Reactions of Bisperoxovanadates Reactions of Monoperoxovanadates with Heteroligands Oxygen Transfer Reactions of Peroxovanadates AQUEOUS REACTIONS AND NMR SPECTROSCOPY OF HYDROXAMIDOVANADATE Vanadium NMR Spectroscopy of Hydroxamido Complexes REACTIONS OF OLIGOVANADATES The Smaller Oligomers Decavanadate INFLUENCE OF LIGAND PROPERTIES ON PRODUCT STRUCTURE AND REACTIVITY Alkyl Alcohols Glycols, a-Hydroxy Acids, and Oxalate Bisperoxo and Bishydroxamido Vanadates: Heteroligand Reactivity Phenols Diethanolamines Pattern of Reactivity VANADIUM IN BIOLOGICAL SYSTEMS Distribution in the Environment Vanadium-Ligand Complexes Vanadium Transport and Binding Proteins Vanadium Containing Enzymes THE INFLUENCE OF VANADIUM COMPOUNDS ON BIOLOGICAL SYSTEMS Vanadium Compounds on Biological Systems: Cellular Growth, Oxidation-Reduction Pathways, and Enzymes Metabolism Pharmacological Properties of Vanadium Mechanism of Therapeutic and Apoptotic Effects of Vanadium Summary Abbreviations TECHNOLOGICAL DEVELOPMENT Molecular Networks and Nanomaterials The Vanadium Redox Battery The Silver Vanadium Oxide Battery PREPARATION, CHARACTERIZATION, AND BATTERY APPLICATIONS OF SILVER VANADIUM OXIDE MATERIALS Introduction Preparation, Structure, and Reactivity of Silver Vanadium Oxide and Related Materials Battery Applications of Silver Vanadium Oxide Summary *Each Chapter Contains References