Isotope Effects In Chemistry and Biology

ISBN: 9780824724498 出版年：2005 页码：1,092 CRC Press

Editorial Biography Theoretical Basis of Isotope Effects from an Autobiographical Perspective J. Bigeleisen Enrichment of Isotopes T. Ishida and Y. Fujii Comments on Selected Topics in Isotope Theoretical Chemistry M. Wolfsberg Condensed Matter Isotope Effects W.A. Van Hook Anharmonicities, Isotopes, and IR and NMR Properties of Hydrogen-Bonded Complexes J.E. Del Bene Isotope Effects on Hydrogen-Bond Symmetrization in Ice and Strong Acids at High Pressure K. Aoki Hydrogen Bond Isotope Effects Studied by NMR H-H. Limbach, G.S. Denisov and N.S. Golubev Isotope Effects and Symmetry of Hydrogen Bonds in Solution: Single- and Double-Well Potential J.S. Lau and C.L. Perrin NMR Studies of Isotope Effects of Compounds with Intramolecular Hydrogen Bonds P.E. Hansen Vibrational Isotope Effects in Hydrogen Bonds Z. Mielke and L. Sobczyk Isotope Selective Infrared Spectroscopy and Intramolecular Dynamics M. Hippler and M. Quack Nonmass-Dependent Isotope Effects R.E. Weston, Jr. Isotope Effects in the Atmosphere E. Roth, R. Letolle, C. M. Stevens, and F. Robert Isotope Effects for Exotic Nuclei O. Matsson Muonium - An Ultra-Light Isotope of Hydrogen E. Roduner The Kinetic Isotope Effect in the Photo-Dissociation Reaction of Excited-State Acids in Aqueous Solutions E. Pines The Role of an Internal-Return Mechanism on Measured Isotope Effects H.F. Koch Vibrationally Enhanced Tunneling and Kinetic Isotope Effects in Enzymatic Reactions S.D. Schwartz Kinetic Isotope Effects for Proton-Coupled Electron Transfer Reactions S. Hammes-Schiffer Kinetic Isotope Effects in Multiple Proton Transfer Z. Smedarchina, W. Siebrand, and A. Fernandez-Ramos Interpretation of Primary Kinetic Isotope Effects for Adiabatic and Nonadiabatic Proton-Transfer Reactions in a Polar Environment P.M. Kiefer and J.T. Hynes Variational Transition-State Theory and Multidimensional Tunneling for Simple and Complex Reactions in the Gas Phase, Solids, Liquids, and Enzymes D.G. Truhlar Computer Simulations of Isotope Effects in Enzyme Catalysis A. Warshel, Mats H. M. Olsson, and J. Villa-Freixa Chapter 24 Oxygen-18 Isotope Effects as a Probe of Enzymatic Activation of Molecular Oxygen Justine P. Roth and Judith P. Klinman Chapter 25 Solution and Computational Studies of Kinetic Isotope Effects in Flavoprotein and Quinoprotein Catalyzed Substrate Oxidations as Probes of Enzymic Hydrogen Tunneling and Mechanism J. Basran, L. Masgrau, M.J. Sutcliffe, and N.S. Scrutton Proton Transfer and Proton Conductivity in Condensed Matter Environment A.M. Kuznetsov and J. Ulstrup Mechanisms of CH-Bond Cleavage Catalyzed by Enzymes W. Siebrand and Z. Smedarchina Kinetic Isotope Effects as Probes for Hydrogen Tunneling in Enzyme Catalysis A. Kohen Hydrogen Bonds, Transition-State Stabilization, and Enzyme Catalysis R.L. Schowen Substrate and pH Dependence of Isotope Effects in Enzyme Catalyzed Reactions W.E. Karsten and P.F. Cook Catalysis by Alcohol Dehydrogenases B.V. Plapp Effects of High Hydrostatic Pressure on Isotope Effects D.B. Northrop Solvent Hydrogen Isotope Effects in Catalysis by Carbonic Anhydrase: Proton Transfer through Intervening Water Molecules D.N. Silverman and I. Elder Isotope Effects from Partitioning of Intermediates in Enzyme-Catalyzed Hydroxylation Reactions Paul F. Fitzpatrick Chlorine Kinetic Isotope Effects on Biological Systems P. Paneth Nucleophile Isotope Effects V.E. Anderson, A.G. Cassano, and M.E. Harris Enzyme Mechanisms from Isotope Effects W. W. Cleland Catalysis and Regulation in the Soluble Methane Monooxygenase System: Applications of Isotopes and Isotope Effects J.D. Lipscomb Secondary Isotope Effects A.C. Hengge Isotope Effects in the Characterization of Low Barrier Hydrogen Bonds P.A. Frey Theory and Practice of Solvent Isotope Effects D.M. Quinn Enzymatic Binding Isotope Effects and the Interaction of Glucose with Hexokinase B.E. Lewis and V.L. Schramm Index