Preface to the Wiley Series on Electrocatalysis and Electrochemistry vii Foreword ix by Masatoshi Osawa Preface xi Contributors xiii Part One Nonlinear Vibrational Spectroscopy 1. Water Hydrogen Bonding Dynamics at Charged Interfaces Observed with Ultrafast Nonlinear Vibrational Spectroscopy 3 Emily E. Fenn and Michael D. Fayer 2. SFG Studies of Oxide Water Interfaces: Protonation States, Water Polar Orientations, and Comparison with Structure Results from X-Ray Scattering 48 Y. Ron Shen and Glenn A. Waychunas 3. Vibrational Sum Frequency Generation Spectroscopy of Interfacial Dynamics 85 Christopher M. Berg and Dana D. Dlott 4. Spectroscopy of Electrifi ed Interfaces with Broadband Sum Frequency Generation: From Electrocatalysis to Protein Foams 120 Bjorn Braunschweig, Prabuddha Mukherjee, Robert B. Kutz, Armin Rumpel, Kathrin Engelhardt, Wolfgang Peukert, Dana D. Dlott, and Andrzej Wieckowski Part Two Raman Spectroscopy 5. Surface-Enhanced Resonance Raman Scattering (SERRS) Studies of Electron-Transfer Redox-Active Protein Attached to Thiol-Modified Metal: Case of Cytochrome c 153 Agata Krolikowska 6. Depolarization of Surface-Enhanced Raman Scattering Photons from a Small Number of Molecules on Metal Surfaces 220 Fumika Nagasawa, Mai Takase, Hideki Nabika, and Kei Murakoshi Part Three IRRAS Spectroscopy (Including PM IRRAS) 7. DFT and In Situ Infrared Studies on Adsorption and Oxidation of Glycine, l-Alanine, and l-Serine on Gold Electrodes 241 Andrea P. Sandoval, Jose Manuel Orts, Antonio Rodes, and Juan M. Feliu 8. Composition, Structure, and Reaction Dynamics at Electrode Electrolyte Interfaces Using Infrared Spectroscopy 266 Angel Cuesta 9. Vibrational Stark Effect at Halide Precovered Cu(100) Electrodes 307 Melanie Roefzaad, Duc Thanh Pham, and Klaus Wandelt 10. Vibrational Spectroscopy of the Ionomer Catalyst Interface 327 Ian Kendrick, Jonathan Doan, and Eugene S. Smotkin 11. In Situ PM IRRAS Studies of Biomimetic Membranes Supported at Gold Electrode Surfaces 345 Annia H. Kycia, ZhangFei Su, Christa L. Brosseau, and Jacek Lipkowski Index 418
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