Functionalised N-Heterocyclic Carbene Complexes

ISBN: 9780470712153 出版年：2010 页码：365 Olaf Kuhl Wiley

Abbreviations. Introduction. Chapter 1 The Nature of N-Heterocyclic Carbenes. 1.1 Synthesis. 1.2 Properties of NHC. References. Chapter 2 Why Functionalisation? 2.1 Phosphane Mimick. 2.2 Hemilability. 2.3 Chirality. 2.4 Ligand Geometry. 2.5 Catalysis. References. Chapter 3 N-Heterocyclic with Neutral Tethers. 3.1 Amine Functionalities. 3.2 Oxygen-Containing Groups. 3.3 Phosphane Functionalities. 3.4 Bis-Carbene Ligands. 3.5 Tris-N-Heterocyclic Carbene Ligands. 3.6 Pincer Carbenes. References. Chapter 4 N-Heterocyclic with Anionic Functional Groups. 4.1 Oxygen-Containing Groups. 4.2 Nitrogen-Containing Groups. 4.3 NHC Ligands Incorporating Cp Moieties. 4.4 Transition Metal NHC Complexes Involved in the Activation of C-H Bonds. 4.5 Immobilisation of the Catalyst. 4.6 Sulfur-Containing Functional Groups. References. Chapter 5 Chiral N-Heterocyclic Carbenes. References. Chapter 6 Natural Products. 6.1 Thiazole. 6.2 Amino Acids. 6.3 Purines and Xanthines. 6.4 Carbohydrates. 6.5 Miscellaneous. References. Index.