Additives in Polymers —— Industrial Analysis and Applications

----- 聚合物中的添加剂:工业分析与应用

ISBN: 9780470850626 出版年:2005 页码:837 Jan C J Bart Wiley

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内容简介

Foreword.Preface.About the Author.Acknowledgements.Chapter 1: Introduction.1.1 Additives.1.2 Plastics formulations .1.3 Economic impact of polymer additives.1.4 Analysis of plastics.1.5 Bibliography.1.6 References.Chapter 2: Deformulation Principles.2.1 Polymer identification.2.2 Additive analysis of rubbers: 'Best Practice'.2.3 Polymer extract analysis.2.4 In situ polymer/additive analysis.2.5 Class-specific polymer/additive analysis.2.6 Bibliography.2.7 References.Chapter 3: Sample Preparation Perspectives.3.1 Solvents.3.2 Extraction strategy.3.3 Conventional extraction technologies.3.4 High-pressure solvent extraction methods.3.5 Sorbent extraction.3.6 Methodological comparison of extraction methods.3.7 Polymer/additive dissolution methods.3.8 Hydrolysis.3.9 Bibliography.3.10 References.Chapter 4: Separation Techniques.4.1 Analytical detectors.4.2 Gas chromatography.4.3 Supercritical fluid chromatography.4.4 Liquid chromatography techniques.4.5 Capillary electrophoretic techniques.4.6 Bibliography.4.7 References.Chapter 5: Polymer/Additive Analysis: The Spectroscopic Alternative.5.1 Ultraviolet/visible spectrophotometry.5.2 Infrared spectroscopy.5.3 Luminescence spectroscopy.5.4 High-resolution nuclear magnetic resonance spectroscopy.5.5 Bibliography.5.6 References.Chapter 6: Organic Mass-Spectrometric Methods.6.1 Basic instrumentation.6.2 Ion sources.6.3 Mass analysers.6.4 Direct mass-spectrometric polymer compound analysis.6.5 Ion mobility spectrometry.6.6 Bibliography.6.7 References.Chapter 7: Multihyphenation and Multidimensionality in Polymer/Additive Analysis.7.1 Precolumn hyphenation.7.2 Coupled sample preparation - spectroscopy/spectrometry.7.3 Postcolumn hyphenation.7.4 Multidimensional chromatography.7.5 Multidimensional spectroscopy.7.6 Bibliography.7.7 References.Chapter 8: Inorganic and Element Analytical Methods.8.1 Element analytical protocols.8.2 Sample destruction for classical elemental analysis.8.3 Analytical atomic spectrometry.8.4 X-ray spectrometry.8.5 Inorganic mass spectrometry.8.6 Radioanalytical and nuclear analytical methods.8.7 Electroanalytical techniques.8.8 Solid-state speciation analysis.8.9 Bibliography.8.10 References.Chapter 9: Direct Methods of Deformulation of Polymer/Additive Dissolutions.9.1 Chromatographic methods.9.2 Spectroscopic techniques.9.3 Mass-spectrometric methods.9.4 References.Chapter 10: A Vision for the Future.10.1 Trends in polymer technology.10.2 Trends in additive technology.10.3 Environmental, legislative and regulatory constraints.10.4 Analytical consequences.10.5 Epilogue.10.6 Bibliography.10.7 References.Appendix I: List of Symbols.Appendix II: Functionality of Common Additives Used in Commercial Thermoplastics, Rubbers and Thermosetting Resins.Appendix III: Specimen Polymer Additives Product Sheets.Index.

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