Solution NMR of Paramagnetic Molecules —— Applications to Metallobiomolecules and Models

----- 顺磁性分子的溶液核磁共振:在金属生物分子和模型中的应用

ISBN: 9780444205292 出版年：2001 页码：384 Bertini, Ivano Luchinat, Claudio Parigi, Giacomo Elsevier Science_RM

Selected Contents. Introduction. The hyperfine shift. Relaxation. Chemical exchange, chemical equilibria and dynamics. Transition metal ions: shift and relaxation. Magnetic coupled systems. Nuclear Overhauser effect. Two-dimensional spectra and beyond. Hints on experimental techniques. Appendix I NMR properties of nuclei. Appendix II Dipolar coupling between two spins. Appendix III Derivation of the equations for contact shift and relaxation in a simple case. Appendix IV Derivation of pseudocontact shift in the case of axial symmetry. Appendix V Relaxation by dipolar interaction between two spins. Appendix VI Calculation of (Sz): Curie's law. Appendix VII Derivation of the equations related to NOE. Appendix VIII Magnetically coupled dimers in the high-temperature limit. Appendix IX Product operators: basic tools. Appendix X Reference tables. Subject index.