Photokinetics —— Theoretical Fundamentals and Applications

----- 光动力学:理论基础与应用

ISBN: 9780444825360 出版年:1998 页码:577 Elsevier Science_Series

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内容简介

Stoichiometry of chemical reactions. Photophysics. Photochemistry and photokinetics. Disposition of chapters. General Approach in Formal Kinetics . Fundamentals. General approach to linear systems of reactions. Information about reactions supplied by graphs. Applications to selected systems. Methods of approximations. Special Considerations for Simple and Complex Photoreactions . Relationship between quantum yield and mechanism. Explicit differential equations in photokinetics. The Integration of the differential equation. Photoreactions in viscous media. Survey on approaches for selected examples. Experimental Techniques in Photokinetic Analysis . Introduction. Absorption measurement. Fluorescence measurements. Reflectance measurements. Chromatographic methods. Special methods. Process control in kinetics. Determination of intensity of irradiation. Applications of Kinetic Analysis of Photoreactions . Evaluation of measurements of concentrations. Evaluation of linear dependent measured values. Evaluation of absorbance-time measurements. Fluorescence. Combination of methods. Photoreactions in viscous material. Appendix . Reaction scheme. Simple photochemical reaction. Simple thermal reactions. Examples for the determination of concentrations. Consecutive reactions with superimposed back-reactions. Relationship between quantum yield and photo-mechanism. Example of photokinetic evaluation. Literature .

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