Electrochemical Reactions and Mechanisms in Organic Chemistry

ISBN: 9780444720078 出版年：2000 页码：415 Grimshaw, J Elsevier Science_RM

1 Electrochemical Oxidation and Reduction of Organic Compounds: General Technique Anode and Cathode Materials Kinetics of Electron Transfer Analytical and Spectroscopic Techniques Pulse Radiolysis. 2 Oxidation of Alkanes, Haloalkanes and Alkenes: Radical-Cations Oxidation of Alkanes Oxidation of Haloalkanes Oxidation of Alkenes Intramolecular Cyclization Electrochemically Generated Reagents for Alkenes. 3 Alkenes and Phenylalkenes: Alkene Radical-Anions as Nucleophiles Activated Alkenes - Introduction Activated Alkenes - Dimerization in Aprotic Media Activated Alkenes - Dimerization in Protic Media B-Unsaturated Aldehydes and Ketones Intramolecular Cyclization Mixed Hydrocoupling Reactions Asymmetric Reduction Electrocatalytic Hydrogenation. 4. Reductive Bond Cleavage Processes - I: Dissociative Electron Transfer Reduction of Alkyl and Benzyl Halides Reactions of the Trichloremethyl Group Reductive Cyclization of B-Dihaloalkanes Alkenes from 1,2-Dibromides and Related Compounds Reduction of Aryl Halides Electrochemically Induced SRN1 Reaction Electrochemically Induced Radical Cyclization Reactions of Aryl Halides Carbon-Halogen Bond Reactions Catalysed by the Anode Material Carbon-Halogen Bond Reactions Catalysed by Ni, Co and Pd Complexes Reactions with Carbon Dioxide.